I had to look up maximizer concrete. I don't think I've ever seen it in Australia.
Anyway, the SDS I found for SAKRETE brand says it is based on Portland Cement.
I don't think it right for the job.
Most people who cast/mould domes with Portland cement for binder include an equal amount of slaked lime (calcium hydroxide) so, when the heat inevitably weakens the Portland cement, the lime, which will have begun converting to limestone (calcium carbonate) will offer some strength.
Anyway, it's done now, so may as well carry on and see what happens.
I would put any extra layers on wet to wet.
An important consideration is that lots of cement based things shrink when they dry, so it would be best if it all shrank together.
I don't think the floor is going to work well with mortar mixed with fireclay. I suggest firebrick splits.